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Growth and alteration of uranium-rich microlite

Authors: 
Gieré R., Swope R.J., Buck E.C., Guggenheim R., Mathys D., Reusser E.
Year: 
2 000
Source: 
Materials Research Society, Symposium Proceedings
Abstract: 
Uranium-rich microlite, a pyrochlore-group mineral, occurs in 440 Ma old lithium pegmatites of the Mozambique Belt in East Africa. Microlite exhibits a pronounced growth zoning, with a U-free core surrounded by a U-rich rim (UO2 up to 17 wt.%). The core exhibits conjugate sets of straight cracks (cleavage planes) which provided pathways for a late-stage U-enriched pegmatitic fluid which interacted with the U-free microlite to produce a distinct U enrichment along the cracks and led to the formation of the U-rich rim. Following the stage of U incorporation into microlite, a second generation of hydrothermal fluids deposited mica along the cleavage planes. Subsequent to these two hydrothermal stages, the host rock was uplifted and subjected to intense low-temperature alteration during which Na, Ca and F were leached from the microlite crystals. This alteration also led to a hydration of microlite, but there is no evidence of U loss. These low-temperature alteration effects were only observed in the U-rich rim which is characterized by a large number of irregular cracks which are most probably the result of metamictization, as indicated by electron diffraction images and powder X-ray patterns.
EES Authors: 
Reto Gieré

Department of Earth and Environmental Science / University of Pennsylvania, 251 Hayden Hall, 240 South 33rd Street, Philadelphia, PA 19104-6316