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The sorption mechanisms of zinc to calcium silicate hydrate: Sorption and microscopic investigations

Ziegler F., Gieré R., Johnson C.A.
2 001
Environmental Science & Technology
Knowledge of the binding mechanisms of heavy metals to cement minerals is essential for the prediction of the long-term leachability of secondary building materials and cement-stabilized wastes containing heavy metals. In this study, the sorption of Zn(II) to calcium silicate hydrate (C-S-H(I)) in pre-equilibrated aqueous suspensions has been investigated as a function of time (up to 87 d), pH (11.7, 12.48, and 12.78) and Zn(II) concentration (4.8−4800 μM). Electron probe microanalysis (EPMA) was performed in order to determine where Zn(II) was bound. At high Zn(II) concentrations (>1000 μM), the precipitation of β2-Zn(OH)2 (<pH 12) and calcium zincate (Zn2Ca(OH)6·2H2O, >pH 12) was observed. Surface precipitation could not be discerned. At lower concentrations, it was found that the sorption process was initially very rapid with over 50% sorbed within 30 min but that the sorption continued more slowly to at least 87 d. The data could be interpreted in terms of the Freundlich isotherm up to a Si:Zn(II)sorbed atomic ratio of approximately 6:1. Zinc was observed by EPMA to incorporate into the C-S-H(I) particles but did not appear to substitute for Ca or Si. The incorporation of Zn(II) in the interlayer of C-S-H(I) or sorption to internal surfaces of crystalline appear to be the most probable mechanisms for the observed Zn(II) sorption to C-S-H(I).
EES Authors: 
Reto Gieré

Department of Earth and Environmental Science / University of Pennsylvania, 251 Hayden Hall, 240 South 33rd Street, Philadelphia, PA 19104-6316