weathering

Streams of the Montane Humid Tropics. Treatise on Geomorphology

Scatena F.N., Gupta A., 2011. Streams of the Montane Humid Tropics. Treatise on Geomorphology. Editors E. Wohl. Academic Press, San Diego Ca. Vol 9. in press April 2011

Abstract: 
Tropical montane streams produce a disproportionately large amount of the sediment and carbon that reaches coastal regions and have often been considered to be distinct fluvial systems. They typically drain orogenic terrains that have not been recently glaciated, but have undergone climatic changes throughout the Pleistocene and currently receive 2000–3000 mm or more of precipitation each year. Steep gradient reaches with numerous boulders, rapids, and waterfalls that alternate with lower gradient reaches flowing over weathered rock or a thin veneer of coarse alluvium characterize these streams. Although their morphology and hydrology have distinctive characteristics, they do not appear to have diagnostic landforms that can be solely attributed to their low-latitude locations. While they are relatively understudied, an emerging view is that their distinctiveness results from a combination of high rates of chemical and physical weathering and a high frequency of significant geomorphic events rather than the absolute magnitudes of individual floods or other geomorphic processes. Their bedrock reaches and abundance of large and relatively immobile boulders combined with their ability to transport finer-grained sediment also suggest that the restorative processes in these systems may be less responsive than in other fluvial systems.

Long‐term patterns and short‐term dynamics of stream solutes and suspended sediment in a rapidly weathering tropical watershed

Shanley, J. B., W. H. McDowell, and R. F. Stallard (2011), Long‐term patterns and short‐term dynamics of stream
solutes and suspended sediment in a rapidly weathering tropical watershed, Water Resour. Res., 47, W07515,
doi:10.1029/2010WR009788

Abstract: 
The 326 ha Río Icacos watershed in the tropical wet forest of the Luquillo Mountains, northeastern Puerto Rico, is underlain by granodiorite bedrock with weathering rates among the highest in the world. We pooled stream chemistry and total suspended sediment (TSS) data sets from three discrete periods: 1983–1987, 1991–1997, and 2000–2008. During this period three major hurricanes crossed the site: Hugo in 1989, Hortense in 1996, and Georges in 1998. Stream chemistry reflects sea salt inputs (Na, Cl, and SO4), and high weathering rates of the granodiorite (Ca, Mg, Si, and alkalinity). During rainfall, stream composition shifts toward that of precipitation, diluting 90% or more in the largest storms, but maintains a biogeochemical watershed signal marked by elevated K and dissolved organic carbon (DOC) concentration. DOC exhibits an unusual “boomerang” pattern, initially increasing with flow but then decreasing at the highest flows as it becomes depleted and/or vigorous overland flow minimizes contact with watershed surfaces. TSS increased markedly with discharge (power function slope 1.54), reflecting the erosive power of large storms in a landslide‐prone landscape. The relations of TSS and most solute concentrations with stream discharge were stable through time, suggesting minimal long‐term effects from repeated hurricane disturbance. Nitrate concentration, however, increased about threefold in response to hurricanes then returned to baseline over several years following a pseudo first‐order decay pattern. The combined data sets provide insight about important hydrologic pathways, a long‐term perspective to assess response to hurricanes, and a framework to evaluate future climate change in tropical ecosystems.

Sr isotopes as a tracer of weathering processes and dust inputs in a tropical granitoid watershed, Luquillo Mountains, Puerto Rico

Pett-Ridge J. C., Derry L. A. and Kurtz A. C. (2009) Sr isotopes as
a tracer of weathering processes and dust inputs in a tropical
granitoid watershed, Luquillo Mountains, Puerto Rico. Geochim.
Cosmochim. Acta 73, 25–43.

Abstract: 
Sr isotope data from soils, water, and atmospheric inputs in a small tropical granitoid watershed in the Luquillo Mountains of Puerto Rico constrain soil mineral development, weathering fluxes, and atmospheric deposition. This study provides new information on pedogenic processes and geochemical fluxes that is not apparent in watershed mass balances based on major elements alone. 87Sr/86Sr data reveal that Saharan mineral aerosol dust contributes significantly to atmospheric inputs. Watershed-scale Sr isotope mass balance calculations indicate that the dust deposition flux for the watershed is 2100 ± 700 mg cm2 ka1. Nd isotope analyses of soil and saprolite samples provide independent evidence for the presence of Saharan dust in the regolith. Watershed-scale Sr isotope mass balance calculations are used to calculate the overall short-term chemical denudation velocity for the watershed, which agrees well with previous denudation rate estimates based on major element chemistry and cosmogenic nuclides. The dissolved streamwater Sr flux is dominated by weathering of plagioclase and hornblende and partial weathering of biotite in the saprock zone. A steep gradient in regolith porewater 87Sr/86Sr ratio with depth, from 0.70635 to as high as 0.71395, reflects the transition from primary mineral-derived Sr to a combination of residual biotite-derived Sr and atmospherically-derived Sr near the surface, and allows multiple origins of kaolinite to be identified

Weathering of the Rio Blanco quartz diorite, Luquillo Mountains, Puerto Rico: Coupling oxidation, dissolution, and fracturing

Buss HL, Sak PB, Webb SM, Brantley SL. 2008. Weathering of the Rio
Blanco quartz diorite, Luquillo Mountains, Puerto Rico: coupling
oxidation, dissolution, and fracturing. Geochimica et Cosmochimica
Acta 72: 4488–4507.

Abstract: 
In the mountainous Rio Icacos watershed in northeastern Puerto Rico, quartz diorite bedrock weathers spheroidally, producing a 0.2–2 m thick zone of partially weathered rock layers (2.5 cm thickness each) called rindlets, which form concentric layers around corestones. Spheroidal fracturing has been modeled to occur when a weathering reaction with a positive DV of reaction builds up elastic strain energy. The rates of spheroidal fracturing and saprolite formation are therefore controlled by the rate of the weathering reaction. Chemical, petrographic, and spectroscopic evidence demonstrates that biotite oxidation is the most likely fractureinducing reaction. This reaction occurs with an expansion in d (001) from 10.0 to 10.5A ˚ , forming ‘‘altered biotite”. Progressive biotite oxidation across the rindlet zone was inferred from thin sections and gradients in K and Fe(II). Using the gradient in Fe(II) and constraints based on cosmogenic age dates, we calculated a biotite oxidation reaction rate of 8.2  1014 mol biotite m2 s1. Biotite oxidation was documented within the bedrock corestone by synchrotron X-ray microprobe fluorescence imaging and XANES. X-ray microprobe images of Fe(II) and Fe(III) at 2 lm resolution revealed that oxidized zones within individual biotite crystals are the first evidence of alteration of the otherwise unaltered corestone. Fluids entering along fractures lead to the dissolution of plagioclase within the rindlet zone. Within 7 cm surrounding the rindlet–saprolite interface, hornblende dissolves to completion at a rate of 6.3  1013 mol hornblende m2 s1: the fastest reported rate of hornblende weathering in the field. This rate is consistent with laboratory-derived hornblende dissolution rates. By revealing the coupling of these mineral weathering reactions to fracturing and porosity formation we are able to describe the process by which the quartz diorite bedrock disaggregates and forms saprolite. In the corestone, biotite oxidation induces spheroidal fracturing, facilitating the influx of fluids that react with other minerals, dissolving plagioclase and chlorite, creating additional porosity, and eventually dissolving hornblende and precipitating secondary minerals. The thickness of the resultant saprolite is maintained at steady state by a positive feedback between the denudation rate and the weathering advance rate driven by the concentration of pore water O2 at the bedrock–saprolite interface.

Controls on major solutes within the drainage network of a rapidly 3 weathering tropical watershed

Bhatt, M. P., and W. H. McDowell (2007), Controls on major solutes within the drainage network of a rapidly weathering
27 tropical watershed, Water Resour. Res., 43, XXXXXX, doi:10.1029/2007WR005915.

Abstract: 
Surface water chemistry in the main stem and source points of the Rio Icacos basin 7 (Luquillo Experimental Forest, Puerto Rico) was studied to investigate the factors 8 regulating spatial variability in major solutes in a rapidly weathering landscape. We 9 sampled along the main stem as well as at small source points at high elevation where 10 fresh bedrock is frequently exposed, and at low elevation in the floodplain/colluvial 11 plain of the main stem. Concentrations of silicon, alkalinity, and the sum of base 12 cations were lower at the source points than in the main stem, and were lowest in low- 13 elevation source points. Calcium and sodium were the dominant cations at all sampling 14 points after sea-salt correction, reflecting the weathering of plagioclase feldspar 15 throughout the basin. The partial pressure of carbon dioxide (pCO2) tended to be higher, 16 and HCO3  concentrations were lower, in the low-elevation source points than at other 17 positions in the landscape. When coupled with the relatively low concentrations of Si and 18 base cations, this suggests that the availability of primary reactive minerals, rather than 19 carbonic acid concentrations, limits weathering in these low-elevation sources. 20 Mechanical denudation appears to enhance chemical weathering rates not only by 21 refreshing reactive mineral surfaces but also by contributing carbon dioxide from the 22 decomposition of organic-rich material in landslides, which occur frequently. The spatial 23 variability of major solutes appears to depend primarily on the availability of fresh primary 24 reactive minerals, carbon dioxide concentrations, and hydrolysis conditions.

REDUCTION OF BEDROCK BLOCKS AS CORESTONES IN THE WEATHERING PROFILE: OBSERVATIONS AND MODEL

Fletcher RC, Brantley SL. 2010. Reduction of bedrock blocks as corestones in the weathering profile: observations
and model. Am. J. Sci. 310:131–64

Abstract: 
the Espiritu Santo and Mameyes rivers within the Luquillo Experimental Forest (Puerto Rico) are interpreted as corestones, reduced from initial joint-bounded bedrock blocks by subsurface weathering. Maximum corestone size, expressed as the geometric mean of the three dimensions, S 3 abc, shows a smooth envelope when plotted against elevation. We postulate that, for each catchment, they represent in situ corestones within a stratified weathering profile, many tens of meters in thickness, that has been subsequently exhumed by younger erosion. We formulate a simplified one-dimensional model for reduction in corestone size within a steady-state weathering profile that incorporates: (i) vertical fluid transport of the reactant and the soluble products of chemical weathering; (ii) linear kinetics of corestone reduction; and, subsequently, (iii) erosion. The rate of advance of a steady-state weathering profile is a statement of the mass balance between entering reactants and weathering components, here idealized as H and albite. The mathematical relations, tie the laboratory-determined rate constant for dissolution of albite (k) to a generalized kinetic constant for the rate of decrease (K) in corestone diameter to the advance rate of the weathering profile (V ). The last parentheses contain an effective roughness at the scale of the weathering profile, where S0 is the maximum size of initial bedrock blocks, inferred to be set by initial bedrock fracture spacing, and 3L* is the profile thickness. The laboratory scale roughness value, , is the ratio of the surface area accessed by BET analysis to that of the corestone grain scale. In the model, erosion is not coupled with weathering, although the presence of corestones of finite size, SE>0, exiting at the erosional surface may be postulated to affect the erosional flux. The thickness of the corestone weathering profile derived for the model for the distance between bedrock and a corestone-free saprolite cap is approximately This expression is the product of the effective pH buffering-adjusted input reactant flux per unit area times a stoichiometeric factor linking this to net albite dissolution, divided by the rate of corestone size reduction at the input concentration of protons. Further, the profile thickness scales with the input “particle” size, S0. The model fit, which yields the ratio is consistent with a rate constant for albite dissolution that lies between laboratorymeasured and field-estimated values. Sensitivity to the reaction order of albite dissolution with respect to H, N, is small, except near the base of the profile. This model yields insights into the relationship between fracture spacing and the evolution of particle size and chemistry in weathering profiles.
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