Photochromism has been observerd as early as 1867. J. Fritzsche
noted the bleaching of orange tetracene in sunlight. E. ter Meer
noticed that potassium dinitroethane changed from yellow to red when
exposed to light in 1876. In 1881, T. Phipson saw that a painted
black post turned white at night. The most notable early
researcher of photochromism was W. Markwald, though. He studied
the color changes of 2,3,4,4-tetrachloronaphthalen-1(4H)-one in
1899. Since he thought the color change was of a physical nature,
he named the color-changing process phototropy. The
study of photochromism resumed in Israel in 1950. Yehuda
Hirshberg came up with the term "photochromism" to describe the color
change associated with light (Bouas-Laurent & Durr).
Corning was the first company to introduce
photochromic lenses. In 1964, their photochromic glass lenses
using silver hit the marketplace. The silver was dispersed evenly
throughout the glass medium. Eventually, Corning also came out
with an organic photochromic line of lenses. The organic dyes
could be evenly mixed throughout the plastic or thinly coated on the
surface of the plastic (Photochromism
Corning).
Trasitions® lenses were introduced in
1990. Between 1991 and 2002, the company released four
generations of photochromic lenses. The Generation 5 lenses,
introduced in 2005, claimed to be clear indoors and as dark as
sunglasses outdoors. In 2008, Generation 6 lenses were
released. These lenses boasted faster transition times (Company
History).